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You might want to check with the local water agency. Alot of Cities and water agencies are no longer adding copper to the water. Therefore resulting in higher Total Alkalinity in the pools. High total alkalinity results in calcium problems!
In regards to tile setting in cold or even near freezing conditions, I would recommend a product called Anti-Hydro.(www.anti-hydro.com) It is a liquid additive that goes directly into your water mix at a certain ratio. We also use it when setting coping in these conditions to prevent freezing of the mortar. They have several products to choose from for different applications. Perhaps a better altenative to calcium.
As far as thinset, a full flex, polymer based material is not a bad choice. It's recommended for glass tile as it properties allow for movement. It's a little more expensive than typical pre-mixed thinset.
I also think waterproofing the structure prior to setting your tile is key. Thoroseal makes a product that is good for "Positive" and "Negative" applications. A 50# bag Gray (T1018) is available from most mason supplies. To get the full benefit of the waterproofing you must add Acrylic 60 and water to the mix at the proper ratio!
This product is our preference as it is a easy process to apply.
I am familiar with Mulasticoat but I don't think it has positive and negative waterproofing features. Plus it's a 2 part process application of the membrane and then an application of a scratch coat. Plus, they recommend waiting 30 days, yes 30 days before applying the product to allow the gunite/shotcrete/concrete to fully cure.
Lastly, the water source at the job site for mixing your materials may have a high mineral content including calcium. Maybe a quick test to determine that may not be a bad idea-just a thought. Most homes in my area that have personal wells or some towns "city" water actually draws from an aquafir have an elevated calcium content.
2 thoughts... could there be movement in the coping allowing for a crack between the coping and the top of the tile? Or could the coping setting bed be getting moisture from the back side, and migrating through and revealing in the tile? Being in the SouthWest we don't have a very significant amount of precipitation. I have seen job photos from other areas of the country where they actually put an elastomeric coating on the back side of the coping, covering the coping material, setting bed, and top of bond beam.
Another thought is to make sure that the formwork that the shotcrete contractor is shooting against is SOLID and can not vibrate which will cause voids in the S/C.
There are some great waterproofing discussions on another site I visit regularly too... http://purewaterpools.com/smf/index.php
Justin Tortorella said:
Mulasticoat is a rubber membrane type of product I believe...?
We have used a similar product to waterproof the backside raised bond beam walls in the past. Thoroughseal though is much easier to work with we have found. With the membrane type product it is so important to get the surface clean, which can be a challenge on a raised planter wall situation. Thoroughseal brushes on easily. Being cementicious though, Thoroughseal is brittle and will crack, whearas Mulasticoat is a flexible membrane which will allow some flex and movement, so there are definite applications for both products.
Make sure you are using whatever product according to the manufacturers spec. though. For instance Thoroughseal is not approved for installations that have negative water pressure, only positive pressure... So make sure you understand which product is appropriate for the specific installation you are working on.
Here is another product line which has been used by others with GREAT results... http://www.laticrete.com/architects/products/waterproofing.aspx
I have heard of guys mixing XYPEX http://www.xypex.com/ in with their mortar beds, and even to the shotcrete itself, but I do not have any firsthand experience with it.
We have been experimenting with a product called mulasticoat that helps to water proof the shell but i am not certain that is the answer either because we just started using it. Have you had any experience with mulasticoat?